Self-organized shortcuts in the Argentine ant

This work is supported in part by the Belgian program on interuniversity attraction poles, Les Instituts Internationaux de Physique et de Chimie, and the Belgian IRSIA grant # 860004.     

Simultaneous determination of three herbicides by differential pulse voltammetry and chemometrics

A novel differential pulse voltammetry method (DPV) was researched and developed for the simultaneous determination of Pendimethalin, Dinoseb and sodium 5-nitroguaiacolate (5NG) with the aid of chemometrics. The voltammograms of these three compounds overlapped significantly, and to facilitate the simultaneous determination of the three analytes, chemometrics methods were applied. These included classical least squares (CLS), principal component regression (PCR), partial least squares (PLS) and radial basis function-artificial neural networks (RBF-ANN). A separately prepared verification data set was used to confirm the calibrations, which were built from the original and first derivative data matrices of the voltammograms. On the basis relative prediction errors and recoveries of the analytes, the RBF-ANN and the DPLS (D - first derivative spectra) models performed best and are particularly recommended for application. The DPLS calibration model was applied satisfactorily for the prediction of the three analytes from market vegetables and lake water samples.     

Biosorption of thorium on the external shell surface of bivalve mollusks: the role of shell surface microtopography

External shell surface (ESS) of bivalve mollusks is known to adsorb various metals dissolved in ambient water in high concentration. It is hypothesized here that the surface microtopography of the thin organic coating layer, periostracum, or calcareous shell (if periostracum was destroyed) plays a major role in the adsorption of actinides on ESS. Thorium (natural alpha-emitter) was used in short-term biosorption experiment with shell fragments of five bivalve mollusks. After a 72 h exposure to Th (∼6 kBq L⁻¹), thorium concentration was measured on ESS using laser ablation inductively coupled plasma mass spectrometry; the distribution and density of alpha tracks were subsequently visualized by α-track autoradiography. A trend in reduced Th concentrations on the ESS was observed depending upon the species tested: (group 1 ∼4000 μg g⁻¹) Chlamys islandica (M.), Mercenaria mercenaria (L.), Dreissena polymorpha (P.) > (group 2 ∼1200 μg g⁻¹) Crassostrea virginica (G.) ? (group 3 ∼150 μg g⁻¹) Mytilus edulis L. The microtopography of ESS was characterized by scanning electron microscopy revealing the high porosity of the calcareous surface of C. islandica and M. mercenaria, lamellate surface of periostracum in D. polymorpha, uneven but a weakly porous surface of periostracum of C. virginica, and a nearly smooth surface of the periostracum of M. edulis. This work has demonstrated, for the first time, the presence of a strong correlation between concentration of adsorbed Th and ESS microtopography, and the role of the periostracum in this process is discussed.     

Bioconcentration of two pharmaceuticals (benzodiazepines) and two personal care products (UV filters) in marine mussels (Mytilus galloprovincialis) under controlled laboratory conditions

Bioaccumulation is essential for gaining insight into the impact of exposure to organic micropollutants in aquatic fauna. Data are currently available on the bioaccumulation of persistent organic pollutants, but there is very little documentation on the bioaccumulation of pharmaceuticals and personal care products (PPCPs). The bioconcentration of selected PPCPs was studied in marine mussels (Mytilus galloprovincialis). The selected PPCPs were two organic UV filters, i.e., 2-ethylhexyl-4-trimethoxycinnamate (EHMC) and octocrylene (OC), and two benzodiazepines (BZP), i.e., diazepam (DZP) and tetrazepam (TZP). Laboratory experiments were performed in which M. galloprovincialis was exposed to these compounds either directly from water, for the less lipophilic substances (BZP) or via spiked food for lipophilic UV filters. M. galloprovincialis uptook and eliminated BZP following first-order kinetics. The biological half-life (t (1/2)) of TZP was 1.4?days, resulting in a bioconcentration factor of 64 and 99?mL?g(-1) dry weight (dw), respectively, for 2.3 and 14.5?μg?L(-1) of exposure, while the biological half-life (t (1/2)) of DZP was 0.4?days, resulting in a bioconcentration factor of 51?mL?g(-1) dw for 13.2?μg?L(-1) of exposure. The uptake of UV filter was rapid in mussels, followed by elimination within 24?h. EHMC increased from 15 to 138?ng?g(-1) dw in 1?h and decreased to 25?ng?g(-1) after 24?h for 11.9?μg?L(-1) exposure. OC reached 839?ng?g(-1) dw after 1?h and decreased to 33?ng?g(-1) after 24?h for 11.6?μg?L(-1) exposure. However, EHMC and OC were slightly accumulated in 48?h, i.e., 38 and 60?ng?g(-1) dw, respectively.     

Modelling the Choice Between Multiple-Use vs. Specialised Forest Management and its Impact on Forest Management Costs

Forests provide ecosystem services, including timber production. In some cases, private forest owners perform management actions in order to enhance the provision of such services, or they may be encouraged by public policies and payments. This paper focuses specifically on the decision to set forest land aside for biodiversity conservation, as part of the more general question of the efficiency of multiple-use vs. specialised management of forest lands. We propose an econometric analysis to identify factors in the set-aside choice and measure the impact of this decision on forest management costs. The results show that the set-aside choice depends on the landowners’ income and motivations related to forest amenities. The choice of specialised management, as reflected in the set-aside decision, has a significant and positive impact on the intensity of management in the remainder of the forest and on management costs. From a policy implications point of view, these results suggest that instruments such as forest certification, subsidies and reverse auctions for conservation will be most likely to attract the interest of those forest owners with personal motivations and forest properties that offer both benefit and cost advantages in opting for such specialised management strategies.

     

Atmospheric Polycyclic Aromatic Hydrocarbons at a Point Source of Emissions. Part A: Identification and Determination of Polycyclic Aromatic Compounds in Airborne Particulate Matter Near a Horizontal Stud Soderberg Plant

Abstract

This paper summarizes the sampling and analytical methods developed to identify and measure polycyclic aromatic hydrocarbons (PAH) and related aromatic compounds near a Horizontal Stud Soderberg plant at Jonquiere, Quebec, Canada. The primary source of PAH is the coal tar pitch used as a binder in Soderberg anodes. Twice a week at a number of sampling sites, airborne particulate matter was collected on glass-fiber filters using a Hi-Vol sampler for a twenty-four hour period. Organics on the filter were Soxhlet extracted with benzene.

Identification was done by gas chromatography-mass spectrometry (GC-MS). The vast majority of compounds present were PAH, but small amounts of alkyl PAH and polycyclic aromatic compounds with heteroatoms such as nitrogen, oxygen and sulfur were also identified. Based on the GC-MS identification, a group of 14 PAH was selected for monitoring. Frequent PAH determinations revealed that the ratio of Benzo(a- )Pyrene to total PAH on the Hi-Vol filters is relatively constant in ambient air from one sampling station to another.     

PROBLEMS IN WEIGHTING OF HYETOGRAPHS1

ABSTRACT: It was found that the conventional weighting factor application to hyetograph ordinates results in artificially attenuated storm patterns. A modified weighting procedure is suggested which allows adjustments in the storm timing, peak intensity, and volume but conserves the storm pattern observed at the raingage nearest to the watershed point of interest. The systematic underestimation of peak flood flows, which result from conventional hyetograph weighting, can be avoided by conserving the hyetograph shape from the raingage nearest to any subarea of a modeled watershed and merely applying weighting factors to the rainfall volumes and temporal center of gravity of several hyetographs.     

PARAMETER ESTIMATION IN HYDROLOGY: THE STATE OF THE ART1

ABSTRACT A detailed review of current methods and criteria used in parameter estimation in hydrology is presented. The effect of errors in the data set and the effect of interactions between methods of analysis, criteria, data set errors, and modeling assumptions are reviewed and discussed briefly. It is concluded that study of techniques, criteria, data set errors and particularly interactions between these, is essential to further progress in hydrologic modeling.     

REGIONAL RAINFALL INTENSITY-DURATION-FREQUENCY CURVES FOR PENNSYLVANIA1

ABSTRACT: A statistical analysis of all available continuous hourly and 15-minute duration rainfall records for Pennsylvania was performed to develop an updated procedure to estimate design storms. As a resuit of this study, Pennsylvania was divided into five homogeneous rainfall regions and a set of rainfall intensity-duration curves developed for each region, for return periods of 1 to 100 years and durations ranging from 5 minutes to 24 hours. The PDT-IDF curves were judged to be a better representation of Pennsylvania rainfall than the nationwide TP-40 maps, particularly for storm events of 10-years and lower return periods. The average time distribution of 24-hour storms in Pennsylvania was found to be well represented by the SCS Type II distribution. The Corps of Engineers SPS 24-hour distribution was found to differ appreciably from both the SCS Type H and the Pennsylvania 24-hour storm distribution. For storm durations between 15 and 90 minutes the standard Yarnell intensity-duration curves closely resemble Pennsylvania storm distributions.     

Contrasted dynamics of northern Labrador tree lines caused by climate change and migrational lag

The northern Québec-Labrador tree lines are the most climatically stressed tree ecosystems of eastern North America. In particular, white spruce (Picea glauca) tree line populations distributed between 56 degrees N and 58 degrees N and 61 degrees W and 66 degrees W show contrasted responses to recent changes in climate according to their geographic position relative to the Labrador Sea. Along the coast, the northernmost latitudinal and altitudinal tree lines responded positively to warming over the last 50 years with invading spruce several tens of meters above the current tree line. In contrast, white spruce tree lines across the wind-exposed Labrador plateau are located much higher in altitude and have receded a few tens of meters beginning around AD 1740-1750 and have not yet recovered. Whereas no field evidence of recent fire and insect damage was found, all inland tree line stands were progressively damaged likely due to mechanical defoliation of wind-exposed trees. Massive tree death in the 19th century caused a reduction in the number of seed-bearing trees, and declining tree lines were not replenished by seedlings. Recent warming reported for northern latitudes has not been strong enough to change the regressive tree line trajectory in interior Labrador. However, white spruce expansion above coastal tree line in the northernmost forest site in Labrador is in line with current climatic trends. It is hypothesized that the species is still advancing toward its potential tree line higher in altitude due to delayed postglacial migration. The slow advance of white spruce in northernmost coastal Labrador is likely caused by the rugged topography of the Torngat-Kaumajet-Kiglapait mountains.